Publication Abstracts

Green and Hutson 1994

Green, S., and J. Hutson, 1994: Spectral line shape parameters for HF in a bath of Ar are accurately predicted by a potential inferred from spectra of the van der Waals dimer. J. Chem. Phys., 100, 891-898, doi:10.1063/1.466571.

An interaction potential for Ar-HF, which was recently determined from extensive spectroscopic data for the van der Waals dimer and which includes dependence on the HF vibrational state, has been used with accurate close-coupling molecular scattering calculations to predict line shape parameters for the pure rotational and the fundamental and first overtone vibrational bands of HF in a bath of Ar. Agreement with experiment is good; in fact, considering inconsistencies among the experimental values, the theoretical values may be the more reliable. This confirms the accuracy of the Ar-HF interaction potential, including the dependence on the HF vibrational level which is sensitively probed by the line shift cross sections.

Export citation: [ BibTeX ] [ RIS ]

BibTeX Citation

@article{gr09300d,
  author={Green, S. and Hutson, J.},
  title={Spectral line shape parameters for HF in a bath of Ar are accurately predicted by a potential inferred from spectra of the van der Waals dimer},
  year={1994},
  journal={J. Chem. Phys.},
  volume={100},
  pages={891--898},
  doi={10.1063/1.466571},
}

[ Close ]

RIS Citation

TY  - JOUR
ID  - gr09300d
AU  - Green, S.
AU  - Hutson, J.
PY  - 1994
TI  - Spectral line shape parameters for HF in a bath of Ar are accurately predicted by a potential inferred from spectra of the van der Waals dimer
JA  - J. Chem. Phys.
VL  - 100
SP  - 891
EP  - 898
DO  - 10.1063/1.466571
ER  -

[ Close ]

• Return to 1994 Publications

• Return to Publications Homepage