Publication Abstracts

Boulet et al. 2006

Boulet, C., J. Boissoles, R.H. Tipping, and Q. Ma, 2006: On the temperature dependence of the integrated intensity of the collision-induced fundamental band of O2-O2. Molec. Phys., 104, 2753-2758, doi:10.1080/00268970600857792.

The temperature dependence of the integrated intensity of the collision-induced fundamental band of O2-O2 pairs has been investigated. For T < 280 K, most of the intensity has been shown to arise through the long-range isotropic quadrupolar mechanism, which leads to a monotonic decrease with increasing T. Recent observations carried out at higher temperature show a small increase in the integrated intensity as T increases. Assuming that this increase in absorption is due to a short-range isotropic overlap dipole and fitting the theoretically calculated results to the experimental data, reasonable values are obtained for the magnitude and range of this dipole. The assumption is tested by calculating the corresponding spectral profiles, and it is found that these are in good agreement with the experimental measurements over the temperature range from 190 K to 350 K.

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BibTeX Citation

@article{bo05100g,
  author={Boulet, C. and Boissoles, J. and Tipping, R. H. and Ma, Q.},
  title={On the temperature dependence of the integrated intensity of the collision-induced fundamental band of O2-O2},
  year={2006},
  journal={Molec. Phys.},
  volume={104},
  pages={2753--2758},
  doi={10.1080/00268970600857792},
}

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RIS Citation

TY  - JOUR
ID  - bo05100g
AU  - Boulet, C.
AU  - Boissoles, J.
AU  - Tipping, R. H.
AU  - Ma, Q.
PY  - 2006
TI  - On the temperature dependence of the integrated intensity of the collision-induced fundamental band of O2-O2
JA  - Molec. Phys.
VL  - 104
SP  - 2753
EP  - 2758
DO  - 10.1080/00268970600857792
ER  -

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