Publication Abstracts

Blackmore et al. 1988

Blackmore, R., S. Green, and L. Monchick, 1988: Polarized D2 Stokes-Raman Q-branch broadened by He: A numerical calculation. J. Chem. Phys., 88, 4113-4119, doi:10.1063/1.453818.

The high pressure dependence of the linewidths of the D2 polarized Q branch of the Stokes Raman ν = 0→1 transition is calculated numerically and compared with the experimental linewidths. These linewidths are computed using the Shafer-Gordon formula for the line broadening cross section. The requisite S matrices are determined from an ab initio D2-He interparticle potential averaged over D2 vibrational wave functions. These wave functions were also calculated with an ab initio D-D potential. Thus, there were no adjustable parameters for the linewidth calculations. In the high pressure limit, the calculated linewidths matched the experimental linewidths to within about 5%.

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BibTeX Citation

@article{bl02000x,
  author={Blackmore, R. and Green, S. and Monchick, L.},
  title={Polarized D2 Stokes-Raman Q-branch broadened by He: A numerical calculation},
  year={1988},
  journal={Journal of Chemical Physics},
  volume={88},
  pages={4113--4119},
  doi={10.1063/1.453818},
}

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RIS Citation

TY  - JOUR
ID  - bl02000x
AU  - Blackmore, R.
AU  - Green, S.
AU  - Monchick, L.
PY  - 1988
TI  - Polarized D2 Stokes-Raman Q-branch broadened by He: A numerical calculation
JA  - J. Chem. Phys.
JO  - Journal of Chemical Physics
VL  - 88
SP  - 4113
EP  - 4119
DO  - 10.1063/1.453818
ER  -

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