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ABSTRACT

Ramaswamy et al. 1978

Ramaswamy, R., H. Rabitz, and S. Green, 1978: Rotational inelasticity in high-energy H2-H2 collisions. Chem. Phys., 28, doi:10.1016/0301-0104(78)80009-3.

Rotational cross sections for transitions in the H2-H2 system have been calculated for energies up to about 2.0 eV and for rotor levels up to j = 11 in the effective potential approximation. The cases of para H2-para H2, ortho H2-ortho H2 and ortho H2-para H2 are considered. Correlations and trends in the cross sections have been examined, and it is shown that the high-energy collisions are dominated by coupling effects. The results of this analysis also suggest that the collision process may be profitably viewed as a diffusion of probability among the levels.

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