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ABSTRACT

Johns et al. 1976

Johns, J.W.C., W.A. Kreiner, and J. Susskind, 1976: Measurement and analysis of the ν4 band of silane. J. Molec. Spectrosc., 60, 400-411, doi:10.1016/0022-2852(76)90143-0.

The ν4 band of silane has been recorded with a resolution of about 0.06 /cm in the region from 850 to 950 /cm. Assignments of all allowed transitions in this range with J' ≤ 12 have been made on the basis of frequency and relative intensity. Qualitative agreement with theory is good but quantitative agreement begins to break down above J' = 8. The breakdown is attributed to the effects of the strong Coriolis interaction with nearby ν2.

Lines of 29SiH4 and 30SiH4 have been observed in the R branch with constant isotope shifts of -1.334 /cm and -2.600 /cm.

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