Publication Abstracts
Ni et al. 1994
Ni, C.-K., G.W. Flynn, and
, 1994: Experimental and theoretical velocity profiles for pure rotational scattering: CO-hot hydrogen atom collisions. J. Chem. Phys., 101, 9499-9505, doi:10.1063/1.467980.Time dependent diode laser spectroscopy was used to measure Doppler profiles of P-branch lines in the fundamental vibrational band of CO shortly after collisions with H atoms having a translational energy of 2.3 eV. Observed spectral line profiles refelect two Doppler components, a negative room temperature component from molecules out of a given v=0,J state, and a hot component from molecules scattered into the same state. Observed profiles are explained qualitatively using state-to-state differential cross sections calculated from the ab initio potential energy surface of Bowman, Bittman and Harding and a rigid rotor coupled states quantum scattering approximation.
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BibTeX Citation
@article{ni01000b, author={Ni, C.-K. and Flynn, G. W. and Green, S.}, title={Experimental and theoretical velocity profiles for pure rotational scattering: CO-hot hydrogen atom collisions}, year={1994}, journal={Journal of Chemical Physics}, volume={101}, pages={9499--9505}, doi={10.1063/1.467980}, }
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RIS Citation
TY - JOUR ID - ni01000b AU - Ni, C.-K. AU - Flynn, G. W. AU - Green, S. PY - 1994 TI - Experimental and theoretical velocity profiles for pure rotational scattering: CO-hot hydrogen atom collisions JA - J. Chem. Phys. JO - Journal of Chemical Physics VL - 101 SP - 9499 EP - 9505 DO - 10.1063/1.467980 ER -
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