Publication Abstracts
Green and Hutson 1994
, and J. Hutson, 1994: Spectral line shape parameters for HF in a bath of Ar are accurately predicted by a potential inferred from spectra of the van der Waals dimer. J. Chem. Phys., 100, 891-898, doi:10.1063/1.466571.
An interaction potential for Ar-HF, which was recently determined from extensive spectroscopic data for the van der Waals dimer and which includes dependence on the HF vibrational state, has been used with accurate close-coupling molecular scattering calculations to predict line shape parameters for the pure rotational and the fundamental and first overtone vibrational bands of HF in a bath of Ar. Agreement with experiment is good; in fact, considering inconsistencies among the experimental values, the theoretical values may be the more reliable. This confirms the accuracy of the Ar-HF interaction potential, including the dependence on the HF vibrational level which is sensitively probed by the line shift cross sections.
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BibTeX Citation
@article{gr09300d, author={Green, S. and Hutson, J.}, title={Spectral line shape parameters for HF in a bath of Ar are accurately predicted by a potential inferred from spectra of the van der Waals dimer}, year={1994}, journal={Journal of Chemical Physics}, volume={100}, pages={891--898}, doi={10.1063/1.466571}, }
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RIS Citation
TY - JOUR ID - gr09300d AU - Green, S. AU - Hutson, J. PY - 1994 TI - Spectral line shape parameters for HF in a bath of Ar are accurately predicted by a potential inferred from spectra of the van der Waals dimer JA - J. Chem. Phys. JO - Journal of Chemical Physics VL - 100 SP - 891 EP - 898 DO - 10.1063/1.466571 ER -
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